Oh my. Broken a few pins in my time. Takes a little rractice to get used to sorting them out properly.
I've heard of Easy-ADF but never used it. Very likely it defaults to 512 byte sector size.
Here's what CF0 looks like (without the comments);-
FileSystem = l:fat95
Device = compactflash.device
Unit = 0
Flags = 0
LowCyl = 0
HighCyl = 0
Surfaces = 1
BlocksPerTrack = 1
BlockSize = 512
Buffers = 20
BufMemType = 1
BootPri = 0
Stacksize = 4096
Priority = 5
GlobVec = -1
DosType = 0x46415401
I've Bolded the line that selects sector size - 512 bytes is default (good up to 2GB partition size).
2GB up to 16GB you have to change that up to 4096 bytes, 16-32GB it has to be 8192 bytes.
A text editor program like EDIT or Memacs should let you edit the CF0 file. Esc then x to save changes if I recall correctly.
EDIT Devs:Dosdrivers/CF0 <-typed into a shell if you don't have Memacs on your syste should give you a text file editor at least.
There's also a switch you can try setting on the icon to try to get non-compliant cards to work (in the readme of compactflash.device are the details, you can check them at aminet).