Okay, so I checked the voltages;
A4000
O U O 1 2 3
U O U 4 5 6
Is the basic layout. I put the numbers there as reference.
Two and three are ground, black on the adapter, blue on the A4000 PSU.
Pin 1 is 5v, pin 4 is 12v, and pin 5 is -12v. Pin 6 is at 4.33v, but according to this page;
http://www.ianstedman.co.uk/Amiga/amiga_hacks/Amiga_Power_supplies/amiga_power_supplies.html#OrigPSURate it only shows a +12v, -12v and +5v...
The actual ratings I got with my A4000 PSU was 5.01v, 11.45v and -11.98v. pin 6 gave me 4.33v. There wasn't much fluctuation, except when it first powered on. Also of note, I had left the hard drive, floppy drive and CDrom plugged in at this point to draw a little current.
The Silverstone PSU I don't have anything else plugged into, and it was a pretty solid 5v, 12.11v, -11.53~54 and 3.66v
By the way, the CF-IDE adapter is either completely fried, or the CF card is bad. It really does overheat (to the point where it could burn you if you left it on for more than 5-10 minutes. Even if I just plug power into it, it gets really hot. As you mentioned earlier, sounds like there's a short, but I don't see one anywhere, I'll try to look closer, could be that I loosened something under where the power connects that made a connection somewhere.)
I'm about to try swapping out the PSU again and see if it boots (could be the newer PSU detected the short and shut down, where as the A4000's original PSU doesn't have such a feature...)
slaapliedje