Here are some general rules.
#1 Change the fan from the heatsink (placed over the 604e chip) as it is el-cheapo brand and it's only 5VDC. Look for a 40x40x10mm fan which is 12VDC and connect it to one of your free 4-pin PSU connectors.
#2 Be very careful when installing the card into the motherboard fast-slot. Absolutely do not touch the PPC heatsink when pushing down to fix the card securely. This will almost surely damage the sensitive PPC chip underneath. I repeat, do not touch/press down on the PPC heatsink while installing the card!
#3 Will it be an 040 or an 060 on the 68k end? I suspect 060 as you mention overclocking. I suggest getting a heatsink if necessary. You will know by touching the 060 chip after let's say half an hour of usage. If it is as hot as an 040 would be (or close), get a heatsink and maybe a fan too. If you can still leave your finget on the chip without a need to remove it due to burning heat, then you're fine.
#4 Get 4x32MB of 60ns FPM or EDO ram of a quality brand, otherwise if your SIMMs won't be matched in all 4 slots then you must have 2 matching pairs and place them like this:
Slot 1 & 3 matching
Slot 2 & 4 matching
Your A4000 mobo clock jumpers must be set to EXT position. You must have some ram on the card (at least 8mb) in order for the CSPPC to boot, so trying it out without any ram won't produce a boot.
That's all I could think of for now. ;-)
As for the 200Mhz 604e performance, when you are switched to PPC side then things get quite fast. This is especially noticeable with games, however within the OS itself you get some delays in terms of mode switching between the 060 and 604e. Basically, a good example is loading a JPEG image through a WarpJPEG datatype. You double-click on the JPEG file, MultiView tries to open it, detects that WarpJPEG (PPC task) is required, switches to PPC mode, loads the image, switches back to 68k mode. This produces a noticeable delay and doesn't really do justice to the 604e side of things at all, however when something like a game (as I've previously mentioned) is running which is fully PPC oriented, then things become really impressive.