1.3 didn't have a option for switching NTSC/PAL, but since it's really just one bit it's not too hard to do.
Back in the days a typed in a short assembler-listing found in a magazine and put the resulting exe on a bootable floppy.
After booting the A500 would auto-reset (you now had to remove the floppy pretty fast please) and returned in NTSC mode. Pretty nice for WB (couldn't stand 50Hz) or games that didn't use the extra screen real estate offered by PAL.
Note, a PAL-Amiga switched to NTSC is still producing PAL only at 60Hz instead of 50Hz and vice versa.