Usually the CPU (data bus) defines whether the machine is called 16 or 32 bit (think of a PC 386DX with ISA slots - 32 bit). So all earlier Amigas (1000, 500, 2000, 600, CDTV) are 16 bit machines, later/bigger ones (3000, 4000, 1200, CD32) are 32 bit machines.
When it comes to chipsets, OCS/ECS is definitely 16 bit. AGA is partly 32 bit (graphics data), so I'd call it 16/32 bit.
However, the architecture is based on a 32 bit command set with everything appearing 32 bit wide, 32 bit software etc. So I'd call the Amiga per se a 32 bit system.