@AmigaMance,
I've just looked at the connections I've used to hook up to my AT PSU. Using the wires off the AT's 6-wire plug, connect the following:
AT black(1) - Amiga black (thick wire) (0V/Gnd)
AT black(2) - Insulate, not required
AT yellow - Amiga brown (+12V)
AT red - Amiga red (+5V)
AT blue - Amiga white (-12V)
Amiga shield (black thin wire) - Insulate, not connected.
As far as I know, the shield wire can be connected to the PSU's metal casing - but I haven't bothered to do so and there haven't been any ill effects.
Check this link out -
Amiga PSU Guide