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Offline Doobrey

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Re: Diet Cherry Coke
« Reply #14 on: July 13, 2006, 03:50:54 PM »
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bloodline wrote:
Quite possibly the greatest drink I've ever had the pleasure of pouring over my taste-buds...


I just tried some seeing as it got such a glowing review here.
IMHO, I wouldn't say it's the greatest drink ever, but certainly the best diet coke they've made.
 But it suffers from the same things that all the diet cokes (and supermarket own brands) have, it's just too thin and watery compared to normal coke, and still has that horrible artificial sweetner aftertaste to it.

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Unlike "Coke Zero" which is so disgusting I actually felt sick after drinking it.

Luckily it didn't make me sick, to me it just didn't taste of anything..I guess that's why they call it Zero

Anyway, if you happen to have some spare diet coke laying around (approx 200 litres will do) you can always try this

Next up on Amiga.org, Lilt or 7-Up..
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Offline Cymric

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Re: Diet Cherry Coke
« Reply #15 on: July 13, 2006, 04:33:37 PM »
@KArlos:

Reminds me of a friend of mine, who likes to point out that orange juice concentrate is handled as a hazardous and toxic chemical, and is shipped in specifically designed ships and containers. The stuff has a pH of about 0.5.
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Offline bloodlineTopic starter

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Re: Diet Cherry Coke
« Reply #16 on: July 13, 2006, 07:04:24 PM »
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Cymric wrote:
@KArlos:

Reminds me of a friend of mine, who likes to point out that orange juice concentrate is handled as a hazardous and toxic chemical, and is shipped in specifically designed ships and containers. The stuff has a pH of about 0.5.


Nothing compared to Pineapple juice concentrate (Unpasturised)!!!

Offline Karlos

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Re: Diet Cherry Coke
« Reply #17 on: July 13, 2006, 08:40:55 PM »
I've had to handle stuff with a negative pH in the past. Ordinary bronstead style protonatinc acids pale into insignificance next to superacids ;-)
int p; // A
 

Offline Cymric

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Re: Diet Cherry Coke
« Reply #18 on: July 14, 2006, 09:23:43 AM »
Okay, okay, superacids rock (has anyone beaten the power of a HSO3F / SbF5 mixture yet?) but that wasn't my point. My point was that a concentrate of purely natural ingredients can be made to have a pH resembling that of battery acid :). Normally you tend to think of 'natural' acids in terms of weak buffers, diluted, not fully ionised, and the like.

Bloodline, what is the pH of pineapple juice concentrate, then? Pineapple on its own doesn't taste all that sour to me.
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Offline bloodlineTopic starter

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Re: Diet Cherry Coke
« Reply #19 on: July 14, 2006, 10:17:18 AM »
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Cymric wrote:

Bloodline, what is the pH of pineapple juice concentrate, then? Pineapple on its own doesn't taste all that sour to me.


It gets to be about as acidic as as orange juice, but it also conatins bromelain (various proteases) which makes it pretty lethal stuff...

Offline Karlos

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Re: Diet Cherry Coke
« Reply #20 on: July 14, 2006, 11:11:23 AM »
Quote

Cymric wrote:
Okay, okay, superacids rock (has anyone beaten the power of a HSO3F / SbF5 mixture yet?) but that wasn't my point. My point was that a concentrate of purely natural ingredients can be made to have a pH resembling that of battery acid :). Normally you tend to think of 'natural' acids in terms of weak buffers, diluted, not fully ionised, and the like.


HF + SbF5 is a considerably stronger protonating acid than SbF5 activated fluosulfonic acid (which will already dissovle wax!). This is down to the fact that SbF5 sequesters F- on dissociation of HF and point blank refuses to give it back. The resulting SbF6- ion is an extremely weak base and very poor nucleophile. You end up, quite literally with free protons kicking around - it's about 2×10^19 times stronger than 100% sulfuric acid ;-)

Depending on the ratio of HF to SbF5 it retains the ability to dissolve glass and other silicates as well as alkanes and other materials...

Almost as bad as coca cola concentrate ;-)
int p; // A
 

Offline Hyperspeed

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Re: Diet Cherry Coke
« Reply #21 on: July 15, 2006, 01:53:03 AM »
Slightly more worrying is that Lucozade contains Vitamin C (Ascorbic Acid) and preservative (Sodium Benzoate). When combined they have a habit of fermenting to brew Benzine (a cancer causing chemical).

It was on the BBC 6 'O Clock News - Lilt was withdrawn and now appears with a different preservative, yet GlaxoSmithKline still see fit to keep Puke-o-Zade on our shelves under the guise of a 'health' drink.

And remember citizens: Guiness is good for you + smoking is a throat tonic.

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Offline Cymric

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Re: Diet Cherry Coke
« Reply #22 on: July 15, 2006, 03:53:41 PM »
Don't overreact---benzene formation isn't that important unless you keep foddstuffs outside of the fridge in full sunlight. Of course, journalists and consumer agencies are quick to remind us that benzene is a carcinogenic substance, should be forbidden, yaddayaddayadda.

Apparently the problems begin with ascorbic acid being able to react with certain metal ions; the resulting species are able to reduce just one electron away from oxygen; these ions then go on to form OH*-radicals which decarboxylise the benzoate ion to benzene. (This page shows the mechanism.) Problem is: benzoic acid is a natural fungicide, present in a number of berries (cranberries, cloud berries) and other fruits.

So now we have the curious situation that we have two ingredients naturally occurring in a lot of plants which are not allowed to be mixed because it produces a chemical which causes cancer on the long term. I daresay the solution is likely going to come from the fact that we shouldn't eat nor drink anything at all.  :roll: Oh, by the way, be careful with feeding your pet cat anything containing benzoic acid or it derivatives: cats have a much lower tolerance towards this chemical than humans.
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Offline Cymric

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Re: Diet Cherry Coke
« Reply #23 on: July 15, 2006, 07:16:49 PM »
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Karlos wrote:
You end up, quite literally with free protons kicking around - it's about 2×10^19 times stronger than 100% sulfuric acid ;-)

Sounds like the blood of a certain type of alien being killed and resurrected on the white screen for about 4 times...
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Offline Karlos

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Re: Diet Cherry Coke
« Reply #24 on: July 15, 2006, 09:35:37 PM »
Quote

Cymric wrote:
Quote
Karlos wrote:
You end up, quite literally with free protons kicking around - it's about 2×10^19 times stronger than 100% sulfuric acid ;-)

Sounds like the blood of a certain type of alien being killed and resurrected on the white screen for about 4 times...


Unless it's blood vessels were nickel lined (IIRC HF passifies nickel by making a tough surface fluoride) I don't think that particular stuff would be. It's a _lot_ stronger than SbF5 activated triflic acid (FSO3H). Like the latter, it will protonate raw alkanes.

Incidentally, according to something I read recently, modern varieties of carborane based superacids (not actually stronger than the stuff above in dissociation terms but a better source of 'clean' H+ only - ie no dodgy fluorides or other species) might be able to protonate xenon :lol:
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Offline metalman

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Re: Diet Cherry Coke
« Reply #25 on: July 16, 2006, 12:42:57 AM »
Quote

Cymric wrote:
Of course, journalists and consumer agencies are quick to remind us that benzene is a carcinogenic substance, should be forbidden, yaddayaddayadda.

So now we have the curious situation that we have two ingredients naturally occurring in a lot of plants which are not allowed to be mixed because it produces a chemical which causes cancer on the long term.

I daresay the solution is likely going to come from the fact that we shouldn't eat nor drink anything at all.  :roll:


That certainly prevents death caused from cancer!

The average life expectancy in Malawi is 37 years. One quarter of children do not live to see their fifth birthday; 48% of those under five are malnourished.

Malawi's Starve

It's a fact, few people in Malawi die of cancer.

@hyperspeed

Move to Malawi and your benzene worries are over! :P
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Offline Hyperspeed

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Re: Diet Cherry Coke
« Reply #26 on: July 25, 2006, 12:22:54 AM »
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by Cymric:
Don't overreact---benzene formation isn't that important unless you keep foddstuffs outside of the fridge in full sunlight.


The BBC report didn't mention light as being a significant catalyst - the reaction was taking place in storage. And isn't it precisely when there is bright sunshine that people are going to want to drink Lucozade for refreshment?

... that bottle you leave on the beach in the afternoon sun... a ticking cancer timebomb!

(Not to mention new research that suggests the plastics used in the bottle can leak chemicals simular to oestrogen).

When you say benzoic acid is present in fruits, does this mean Sodium Benzoate?

Anyway, the food standards people weren't asking for the Sodium Benzoate to be removed from Lucozade, they wanted the Vitamin C removed for some odd reason. They suggested that there were other opportunities to get this anti-oxidant other than in soft drinks.

In fact, it's either Norway or Sweden has banned Cornflakes as the Vitamin content is deemed a risk to the liver.

But it's Coca Cola's ability to clean tarnished spoons, patios etc. that should pose the greatest warning. Have you noticed too that everyone who drinks Diet Coke is a fat ass?

(Aspartame has been linked to brain cell death as well!)

A good all rounder I've discovered lately is 'Five Alive'. It may be bottled by Coca Cola Enterprises under license but it features none of the crap associated with that American brand.

A good, still and refreshing fruit juice drink in a can with no artificial colours, preservatives or flavourings. It comes in Forest Fruits and Citrus flavours.
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Offline Turambar

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Re: Diet Cherry Coke
« Reply #27 on: July 25, 2006, 09:42:13 AM »
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But it's Coca Cola's ability to clean tarnished spoons, patios etc. that should pose the greatest warning.


As can brown sauce, toothpaste etc.

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Have you noticed too that everyone who drinks Diet Coke is a fat ass?


Perhaps they are on a diet? I know thats a bit of a leap but still....

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A good, still and refreshing fruit juice drink in a can with no artificial colours, preservatives or flavourings.


No its just got a crapload of sugar in it.
 

Offline Cymric

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Re: Diet Cherry Coke
« Reply #28 on: July 25, 2006, 11:35:36 AM »
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Hyperspeed wrote:
Quote
by Cymric:
Don't overreact---benzene formation isn't that important unless you keep foddstuffs outside of the fridge in full sunlight.


[quote[The BBC report didn't mention light as being a significant catalyst - the reaction was taking place in storage. And isn't it precisely when there is bright sunshine that people are going to want to drink Lucozade for refreshment?

It does take place in storage, but much more slowly. Sunlight really provides the 'oompf' for the reaction. Lowering the temperature by 10 degrees cuts the reaction rate in half (old chemist's rule of thumb). But still: it requires a significant amount of sunlight (I recall about a day) before really elevated concentrations of benzene are reached. We're still talking low amounts on an absolute scale, though, and drinking such a bottle of 'spiked' Lucozade won't harm you. Now if you were to ingest gallons upon gallons, yes, then, perhaps.

By the way: I didn't know people stored their drinks in open sunlight... They usually keep them in a bag underneath lots of material so the drink stays cool  :p

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... that bottle you leave on the beach in the afternoon sun... a ticking cancer timebomb!

I think it is about as carcinogenic as walking around in a large city on a hot, sunny afternoon. Phrases like 'ticking cancer timebomb' are nothing but sensational flourish to scare the population.

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(Not to mention new research that suggests the plastics used in the bottle can leak chemicals simular to oestrogen).

Not the phthalate-scare again... This is getting old. The true source of scary phthalates---to make plastic pliable and soft---has been banned from most toys and to my knowledge platics used to store food in. No more source of leaky oestrogenes from that. The second source would be PET, but you need to use really old and really worn bottles (high temperatures, lots of sunlight, lots of agressive liquids, lots of physical stress) in order to coax a little of the material out into the liquid it's containing. It is far likelier that you have a beautiful lining of algae in the bottle long before that happens.

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When you say benzoic acid is present in fruits, does this mean Sodium Benzoate?

Yes. Or another salt, say with potassium or calcium.

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Anyway, the food standards people weren't asking for the Sodium Benzoate to be removed from Lucozade, they wanted the Vitamin C removed for some odd reason. They suggested that there were other opportunities to get this anti-oxidant other than in soft drinks.

That would be a worthwhile suggestion. One of the two chemicals (ascorbic acid or benzoic acid) has to go if you don't want the benzene reaction to occur. It is a bit silly to remove naturally occurring ascorbic acid from fruit juice, but you don't have to exacerbate the problem by adding more.

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In fact, it's either Norway or Sweden has banned Cornflakes as the Vitamin content is deemed a risk to the liver.

Sounds like too much vitamin A or pro-vitamin A, not C. A is known to be a bit of a problem in too high doses: especially pregnant women need to be careful not to overdo it, as it can harm their child. Vitamin C is relatively safe in that regard---at least, I've never heard of any other problem save the benzoic acid one.

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But it's Coca Cola's ability to clean tarnished spoons, patios etc. that should pose the greatest warning. Have you noticed too that everyone who drinks Diet Coke is a fat ass?

I kindly request you not refer to me as a 'fat ass'. According to my girlfriend, my ass is just right: perfect for little slaps and nibbles. I also happen to like my diet Coke quite a lot, thank you very much: it doesn't taste as sweet as regular Coke, and quenches my thirst better because of that.

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(Aspartame has been linked to brain cell death as well!)

What hasn't?

Lately, I've begun switching to water: simple, costs almost nothing, and no health-issues whatsoever.
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Re: Diet Cherry Coke
« Reply #29 from previous page: July 25, 2006, 11:57:46 AM »
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Lately, I've begun switching to water: simple, costs almost nothing, and no health-issues whatsoever.


Couldn't agree more.