Today I made a discovery...
This time a Super Nintendo!
The internet told me I needed to connect each of the R,G,B lines to ground, through 75 ohm resistors, but I decided to leave them out, and see what would happen...
TV reports "Not Supported" and this was a TV that had worked with everything before... (Amiga, MegaDrive, Master System, N64, Gamecube)
Stick the resistors in, works fine! SO I'm thinking the issue with the Kogan TV isn't a sync issue at all....