Castellen, many, many thanks.
I think I sussed it though. ie:
I took the 45Kb HEX image, converted to binary which gave me a 16Kb file.
I opened that in the GQ4X software and copied the block of data to the end of 16Kb.
I then took the 'read' original ROM in the GVP and loaded that, and pasted it 4 times to the chip in the respective correct memory locations to make a 64KB file.
Note the tail end of the GVP ROM ends with two lines of 00 (not FF) so i matched those OK.
I get a boot operation fine with the standard 50MB Quantum SCSI drive BUT i don't get a boot condition with the 1GB Quantum SCSI drive - which could be due to jumpering - jury is out at this stage.
I will have a look at the images you've pointed me at to see how they compare.
Thanks again mate!