Hooray, another potential Envoy user! I've been using Envoy for about a year now, and it really is fantastic. It's very easy to set up, has security if you need it, is very expandable, and is extremely lightweight.
Forget about 100MBPS, as it's just not practical to do on the Amiga. You've got just about everything you need for a 10MBPS network, though, and it's still pretty damn fast. It doesn't *feel* much slower than my hard drives when transfering files, though an actual speed test probably would reveal it to be. Get an Ethernet hub, and plug everything in. I recommend not using DHCP. If you can ping each machine on the network from any other (remember to add hostnames and IP addresses to the Miami database on each machine), you're ready to set up Envoy.
Just run the installer, and have fun. Don't worry about Realms or Gateways. Since you're running it in parallel with Miami, you need to change the IP Type and ARP Types in Envoy to 2049 and 2055 (architecture bug), respectively. There's an Envoy 3.1 patch on Aminet, along with a bunch of additional services for added functionality.