I tried Zorin recently. It was fairly easy to get up and running. It comes with XP and Win7 themes and walks you through the setup with clear graphical instructions. Didnt play much with the preconfigured wine as I just use it for Libre office (pre-installed) and a bit of Counterstike/Darwinia through Steam. The Nvidia graphics drivers have come a long way in the past few months...
I gave the laptop away so I can't say I used it extensively, but it did exactly what I needed it to. It also comes with Chrome, Thunderbird and the Ubuntu App Store, although I had to apt-get the firefox installer as the repository was offline at the time.
