There is no direct access.
Basically Zorro HW initializes and then the resources will be available to the OS via normal OS functions.
There are some low level functions such as expansion.library FindConfigDev() and WriteExpansionByte(), though. Even these only poke the HW in a very controllable and transparent way.
If you want to connect your own device you must implement Zorro2 for it. Refer to the Amiga Hardware Reference Manual, Appendix G, "AUTOCONFIG (TM)".