Well, I do have a 68882 in this so I think that covers the FPU doesn't it?
It's a line F trap/guru. I can think of 3 possibilities:
1) buggy program or library (may be a MUI add-on library)
2) an fpu program or library for the 68040 or 68060 was accidentally installed and it's trying to use the FSOP or FDOP instructions
3) a program or library for the 68040 or 68060 was accidentally installed and it's trying to use the MMU or MOVE16 instructions
If it only happens when running MUI then it may be an MUI add-on library. You can either try installing new versions that may fix it or reinstall MUI and then the add-ons one by one to see if the problem returns.