Well... you can use DOS 6.22's multi-config booting option to have various bootup configs. I did that, had like 3 or 4 configs for various amounts of RAM and memory managers. For instance, Wing Commander liked EMS, I believe. However, many demos didn't want ANY XMS or EMS, just raw memory. Zone66 I think didn't want any EMS. DOS was fast enough booting that it wasn't too much of an issue to reboot when you wanted a different config.
Using DOSBox is like using WinUAE. There's many people who just prefer the real thing. Sure, DOSBox or WinUAE are more accessible, less prone to breaking, portable, and work just fine. But they just don't have as much sex appeal.
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For the SB16 SCSI, I got a refresher myself from:
http://en.wikipedia.org/wiki/Sound_Blaster_16Sound Blaster 16 SCSI-2
Sound Blaster 16 MCD
Sound Blaster 16 Value Edition
Sound Blaster 16 IDE
Sound Blaster 16 ASP (this is what I had)
Sound Blaster 16 WavEffects
Sound Blaster 16 PCI (really an Ensoniq card)
If I recall, the SCSI-2 and IDE interfaces wouldn't boot. So it was a SCSI interface for pretty much only attaching CD-ROMs. I think I read about some people trying to use scanners or tape drives, but I don't recall much in the way of success. Same with hard drives and hard drives on the IDE card.
The MCD/ASP versions had a proprietary CD-ROM interface that did Matsushita and... I think Toshiba and also Panasonic? I think the drives that worked with those cards did not actually work with a "real" IDE interface. If you didn't have the SB16, you were out of luck.
Oh, hey, more digging:
http://www.irlp.net/owners/sb_cards.html"Panasonic, Mitsumi, Sony interface"
Panasonic = Matsushita, durrr. I knew that. Yeah, those were the propietary drives. Not sure if other sound cards jumped on that bandwagon, maybe the Pro Audio Spectrum or some such.
Windows 3.11 stank. I'm happy to not have to deal with Winsock stuff anymore, or set up PPP internet connections. Blargh! Even if it's dog slow, I always try to get Win95 at least as an OS on an old DOS machine mainly for networking ease of use. I'm not quite brave enough to mess with Netware or LANtastic or some of the opensource things like FreeDOS or OpenDOS or whatnot.