there wasn't any difference in my other monitor
Wow, that means your other monitor is also a 15KHz capable (Amiga) monitor. OR it means that your Screen preferences is set to a software scandouble resolution (like double NTSC).... have a go at changing the workbench resolution if you can navigate to it (or at least identify which res it is set to).
and no difference when I toggled the switch
The switch only affects the AMBER (15-pin) output. It switches between 15KHz (off) and 31KHz (on).
Just tried the converter with my 2nd A3000/1950 - the one I couldn't get any picture from - and it worked, but the picture is misaligned and the mouse is showing doubles and triples of it. Any ideas?
Hmmm I wonder why you get no picture on the AMBER output?? Find out what resolution you're in using screen-prefs. Try to change it to something else? Have a go using the overscan controls to re-center the picture?