Mike, you are possibly confused i think

.. he is using 3.1 which the cd0 icon file is a binary file. tooltypes should only be in icon info and you cannot load it into a text editor-dont believe me? grab it off a original workbench storage disk and try and load it into a ed... I just tried this to verify i was right a second ago.
I don't claim to be a expert,but i have been doing this for nearly 20 years on scsi systems(many people argued with me also,until i showed them this works fine).
If the tooltypes are missing in the icon then you either have a modded workbench/disks or something or are not using wb3.1 cd drivers(mikes case). grab the files from the original floppies.
Mike,The example you give is for cache cdfs(not original to workbench 3.1 cdfs). It is a mountlist text file,different from stock cd0 in workbench 3.0 and 3.1.
Mech
P.S. for trivia sake, you can do this also on 3.0.... but the cdfilesystem in L: and cd0: icons are broken,just use them from a 3.1 disk to fix it.