PSU = Power Supply Unit - the power brick
If you're using a multimeter, measure the voltages loaded, i.e. while the PSU is plugged in and the machine is running (or trying to). Just clip the black cord to ground somewhere (e.g. RF shielding), easy access to +5V & +12V is on the floppy power connector. DO NOT short circuit any power pins with their neighbors!
The "Vidiot" hybrid is that black card right next to the Denise chip (upper left corner). It's converting the digital video signals to analog ones for RGB output. Have never seen one die but you never know.
Apart from trying the very easy CIA swap my guess is on one the RAMs or the Agnus socket.
Is the floppy spinning up?
Is the head moving?
How long does it take from inserting the disk to the flashing LED? Anything on the screen then?
Have you tried removing the trapdoor expansion to see if it makes any difference?