I did a test just now, and it didn't boot, into RTG but then I removed the fast RAM so there was only Chip and Z3 and it booted again, so you could try that. (next test it booted with fast ram as well so might have been a spurious one off glitch)
Ah yes, thanks for the hint! I need to disable
Use Zorro 3 RAM, then the a600gs Monitor driver shows up in Screenmode Prefs as it should! As soon as Zorro 3 RAM is enabled A600GS modes are not even listed among Screenmode Prefs modes.
Guess I found a bug? Just don't know whether it's an A600GS bug, an Amiberry bug, an OS 3.2.2.1 bug or a Picasso96 3.5.0 bug...

Probably one of the components hits some internal memory limits? I see 128 MB are used for the RTG card and 1024 MB made available as Fast RAM with
Use Zorro 3 RAM. Could you check if A600GS driver reliably works with e.g. just 512 or 768 MB Z3-RAM or 64 MB RTG as a workaround? IMHO that's more than enough for a Classic Amiga. For the time being I have to stick to 2 MB Chip and 8 MB Fast, which is a bit meagre when running IBrowse or pre-loading larger WHDLoad games with only 4 MB Fast free when using Workbench on 1280x720/8bpp.