On Aminet, there is at least one Level Pack called "the Xenium Core". Very athmospheric.
I also think that Alienbreed3d2 TKG is the best Amiga-FPS ever made. However, there are not really many of them. But after all, it was barely playable on my 60/50MHz, and the gameplay is not really good.
I tried it under WinUAE some time ago, and it was very fast of course, but I realized that many things are not correclty timed, they simply become incredably fast when the FramePerSecond is high, e.g. the animation when reloading the gun.