I am not sure you've measured using the correct ground pin. If there was no 5v you wouldn't get the image of the hand holding the disk on the white background etc. The +5v powers most of the logic chips so 0v would mean nothing happening at all. Put the black wire of the multimeter on signal ground and see what voltages you get, and then try the black wire on the shielding ground and see what you get.
It's sometimes best to actually measure the voltages under the board whilst the amiga is powered up - that way you get 'under load' voltages which can vary wildly from what you measure coming out of the PSU when its not connected to the Amiga. I've seen +16v on 12v line drop to +12v when connected to the amiga etc.
EDIT: I've re-read and realised you said PIN 5, not the 5v line =)
Pin 1 is 5v
Pin 3 is +12v
So your +12v is mega high - could have damaged the FDD or modulator.
And your +5v is very high also - again could have damaged chips.
Check the voltages under load as ive described and use your multimeter on the pins under the board where the socket mounts the PCB. See what you get under load, just to be sure.
Ok, sorry about confusing post. When testing PSU unloaded (not plugged into machine), with black connector on Pin 2, always had a zero rating when red connector put onto Pin 1,3 and 5. So had another look at the diagram and put black connector onto Pin 4 Signal ground, then got those readings.
Have been testing PSU underload, took mother board completely out of machine, but was reluctant to bend back metal casing, as I don't think I'll ever get it back in place.
So worked which pin is coming out through the inside of the connection.
Got some very varied results. When putting black connector on Pin 2, there is some reading, strange how there was nothing when it wasn't plugged into the machine.
Anyway tried lots of the chips and floppy power supply, mono output, etc. Both with black connector on Pin 2, and Pin 4.
The mono output measures 3.5v with both,
RGB output measures 10.4 Down to 3.1, depending which pin red connector is placed on. So I suppose that there is one pin that is the power source for the modulator? You can see that I know absolutely nothing about electronics.
Sorry if this seems too long winded..
Other results are: with black connector on Pin 2;
DENISE 2.0v
ODD CIA varies between 2.3 and 10.6v (depending which pin on chip)
EVEN CIA 10.4v highest
PAULA 10.3v
GARY 10.6v
Trap door 8.6v
Floppy power source 10.6v
And with black connector on Pin 4
DENISE 8.1v
ODD CIA 10.4v
EVEN CIA 10.4v
PAULA 10.3v
GARY 10.6v
Trap door 8.3v
Floppy power source 10.6v
I've realised that certain pins on the chips carry the power, so the low readings should probably be ignored when there is a higher reading across the whole board of around 10.6v?
Hope that makes some sense!