Making some progress now!
I'm rearranging ZORRO cards. My initial card order (bottom to top) was: Toccata, Retina, 256MB Z3 & custom RCA slot cover (for VLM Component & internal Toccata audio connections), and VLM. When you connect the Component Video card to the VLM, you can't put anything in a slot above it, even a small card like the 256MB one. So I was hoping, I could use in the top ZORRO slot and have access to the other 3 slots. I also liked having smaller cards below for better heat dissipation from the motherboard. The VLM is the largest card, full length.
After moving the VLM to the bottom most slot and only installing the Retina. MovieShop launched without problems. MovieShop can be used without an audio card installed. Power down, reinstall the Toccata and the problem came back! I swapped it out with a 2nd Toccata that I have, tried again, and MovieShop worked!.
So, something is wrong with the first Toccata card. This explains why ToccataInit caused problems when placed in WBStartup. I'll have to look this card over another time with another Amiga.
I then went back to the original card order with VLM in the uppermost slot. I really didn't want to loose a slot by placing VLM further down. MovieShop opened successfully with the original slot order.
Thanks to everyone that offered different suggestions. Even if they didn't solve the problem, they gave me some further trouble-shooting ideas and I learned a few new things along the way about the new AmigaOS.
Jaeson