Thank you all for the help.
The good news is, the hangs and crashes are largely gone. Mainly just by improving the cable management and air flow in the case. I have some small cooling parts on order to further maintain the cooling. The a4000 seems to functional well now with an surf and cv64/3D.
The only other issue I now have is a failure to boot at times. I suspect this is down to a faulty chip ram simm, so awaiting on a new one from Amigakit now.
@plaz
Re caps, there appear to be no leaks on the board, however, I have found someone who can do the capping ... And has a repair store just 2km away! Will also get a new PSU or have the caps replaced in the original PSU.
Overall, good to see the a4000 up and running again, thanks all.