There are plenty of utilities out there to align x86 partitions along the 4k page boundaries in SSDs.
Does anything exist for the Amiga to assist in doing so? Should we even consider this important?
Alignment for flash is quite important. However some drives do their best to mitigate the problem, so it's not always entirely obvious.
The alignment for 4k on x86 isn't anything to do with SSDs though, it's because magnetic drives went from 512 byte sectors to 4k sectors. SSDs have even larger sector sizes and often cannot erase a single sector. If the write page size is 32k and the erase size is 1mb then even using a 4k block is still not great.
There isn't much in the way of information on sector sizes and erase size & you may not even be able to tell if you try various options and benchmark them as the drives have been designed to hide it. The wrong settings might affect the lifetime of the SSD, but it's likely that the drive will get written to a lot less than it would in a PC so it might be ok.